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State of a system, 0th law,
equation of state
Work, heat, first law
Internal energy, expansion work
Enthalpy
Adiabatic changes
Thermochemistry
Calorimetry
Second law
Entropy and the Clausius inequality
Entropy and irreversibility
Fundamental equation, absolute S, third law
Criteria for spontaneous change
First hour exam
Gibbs free energy
Multicomponent systems, chemical potential
Chemical equilibrium
Temperature, pressure and Kp
Equilibrium: application to drug design
Phase equilibria — one component
Clausius-Clapeyron equation
Phase equilibria — two components
Second hour exam
Ideal solutions
Non-ideal solutions
Colligative properties
Introduction to statistical mechanics
Partition function (q) — large N limit
Partition function (Q) — many particles
Statistical mechanics and discrete energy levels
Model systems
Applications: chemical and phase equilibria
Introduction to reaction kinetics
Third hour exam
Complex reactions and mechanisms
Steady-state and equilibrium approximations
Chain reactions
Temperature dependence, Ea, catalysis
Enzyme catalysis
Autocatalysis and oscillators
This subject deals primarily with equilibrium properties of macroscopic systems, basic thermodynamics, chemical equilibrium of reactions in gas and solution phase, and rates of chemical reactions.
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